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Supramolecular architecture based on [Fe(CN)6]3− metallotectons and melaminium synthons

Abstract : Assembly involving [Fe(CN)6]3− metallotectons as building units and melaminium organic cation has been envisioned in order to elaborate a hybrid supramolecular based on ionic H-bonds with formula {(H-mel)4[Fe(CN)6]Cl} (H-mel+: melaminium cation). The compound has been prepared by diffusion method and characterized by single-crystal X-ray diffraction, EDX analysis, and Raman-IR spectroscopies with assignment from ab initio calculations. The melaminium exhibit self cationic coupling with cyclic hydrogen bonds to give a one dimensional {[H-mel]+}∝ synthon. Therefore, these cationic ribbons are inter-linked via hydrogen bonds by the anionic tectons [Fe(CN)6]3− and chlorine anion resulting on a 3D network. Molecular hirshfeld surfaces revealed that the crystal structure has been supported mainly by Nsingle bondH⋯N and Nsingle bondH⋯Cl intermolecular Hydrogen bonds and by favoured C⋯C and C⋯N weak interactions.
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https://hal-univ-lemans.archives-ouvertes.fr/hal-02435178
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Soumis le : vendredi 10 janvier 2020 - 16:02:02
Dernière modification le : jeudi 23 juin 2022 - 15:55:13

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Firas Krichen, Siwar Walha, Jérôme Lhoste, Alain Bulou, Ahlem Kabadou, et al.. Supramolecular architecture based on [Fe(CN)6]3− metallotectons and melaminium synthons. Journal of Molecular Structure, Elsevier, 2017, 1146, pp.409-416. ⟨10.1016/j.molstruc.2017.05.123⟩. ⟨hal-02435178⟩

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